Infrared Rotatory Dispersion of Liquid‐Crystalline Solutions of Chiral Molecules
The absolute configuration of molecules with a chiral center can be established by a new empirical procedure: nematic phases of liquid‐crystalline compounds become cholesteric on dissolution of a chiral “guest substance”. The sign of the measured Reflection Cotton Effect provides information whether...
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/10247 |
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| Institution: | Mahidol University |
| Summary: | The absolute configuration of molecules with a chiral center can be established by a new empirical procedure: nematic phases of liquid‐crystalline compounds become cholesteric on dissolution of a chiral “guest substance”. The sign of the measured Reflection Cotton Effect provides information whether the three ligands of greatest priority a > b > c (see priority scheme) are arranged clockwise or counterclockwise. (Figure Presented.) Copyright © 1977 by Verlag Chemie, GmbH, Germany |
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