Synthesis and structural analysis of phenoxy-substituted half-titanocenes with different anionic ligands, Cp*TiX(Y)(O-2,6-ⁱPr<inf>2</inf>C<inf>6</inf>H<inf>3</inf>): Effect of anionic ligands (X,Y) in ethylene/styrene copolymerization

• Main Authors: Kotohiro Nomura, Supathana Pracha, Khamphee Phomphrai, Shohei Katao, Dong Hyun Kim, Hyun Joon Kim, Naohiro Suzuki
• Other Authors: Tokyo Metropolitan University
• Format: Article
• Published: 2018
• Subjects: Chemical Engineering; Chemistry
• Online Access: https://repository.li.mahidol.ac.th/handle/123456789/13902
• Institution: Mahidol University

Synthesis and structural analysis of various phenoxy modified half-titanocenes with different anionic ligands of the type, Cp*TiX(Y)(O-2,6- i Pr 2 C 6 H 3 ) [X = Y = pyr (2, pyr = C 4 H 4 N), pz (3, C 3 H 3 N 2 ), OPh (4); X = Cl, Y = OCH(CF 3 ) 2 (5)] have been explored. Ethylene/styrene copolymeri...