Destannylative pummerer-type rearrangement of 1-(phenylsulfinyl)-1-(tributylstannyl)cyclopropane

• Main Authors: Manat Pohmakotr, Srisamorn Sithikanchanakul
• Other Authors: Mahidol University
• Format: Article
• Published: 2018
• Subjects: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• Online Access: https://repository.li.mahidol.ac.th/handle/123456789/15718

1-(Phenylsulfinyl)-1-(tributylstannyl)cyclopropane on treatment with acyl chlorides or alkyl chloroformate in refluxing dichloromethane afforded 1-acyloxy-1-phenylsulfenyl- and 1-alkoxycarbonyloxy-1-phenylsulfenylcyclopropanes, respectively. The reaction involves the Pummerer-type rearrangement with...