C-H Activation and Palladium Migration within Biaryls under Heck Reaction Conditions

(Equation Presented) Biaryl bromides such as 1 (R=NO2, H, OMe) undergo the Heck reaction to give both the expected products 3 ("retention") as well as "crossover" products 4 derived from a migration of Pd and net transfer of reactivity from one aryl ring to the other. Under the c...

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Bibliographic Details
Main Authors: Gunter Karig, Maria Teresa Moon, Nopporn Thasana, Timothy Gallagher
Other Authors: University of Bristol
Format: Article
Published: 2018
Subjects:
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/20043
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Institution: Mahidol University