Intramolecular acylation of α-sulfinyl carbanion: a facile synthesis of (±)-pentenomycin I and (±)-epipentenomycin I.
(±)-Pentenomycin I and (±)-epipentenomycin I were synthesized, starting from methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate. The key reaction involved the intramolecular acylation of α-sulfinyl carbanion and pyrolysis of the resulting product. © 1991.
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| Main Authors: | , |
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| Format: | Article |
| Published: |
2018
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| Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/21993 |
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| Institution: | Mahidol University |