Diverse pathways of activation and deactivation of half-sandwich aryloxide titanium polymerization catalysts

Diverse pathways of activation and deactivation of half-sandwich aryloxide titanium polymerization catalysts

A series of half-sandwich aryloxide titanium complexes, [CpTi(OAr)Me2] (Cp = C5H5; OAr = OC6H3Me2-2,6, OC6H3Et2-2,6, OC6H3iPr2-2,6, OC6H3tBu2-2,6, and OC6HPh4-2,3,5,6), have been synthesized. These compounds react with B(C6F5)3to give thermally unstable complexes [CpTi(OAr)Me][MeB(C6F5)3]. Two diffe...

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Bibliographic Details
Main Authors: Khamphee Phomphrai, Andrew E. Fenwick, Shalini Sharma, Phillip E. Fanwick, James M. Caruthers, W. Nicholas Delgass, Mahdi M. Abu-Omar, Ian P. Rothwell
Other Authors: Purdue University College of Science
Format: Article
Published: 2018
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/23183
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Institution: Mahidol University

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https://repository.li.mahidol.ac.th/handle/123456789/23183

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