2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals

A simple and efficient procedure has been developed for the oxidation of cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters, respectively. 2-Iodoxybenzoic acid (IBX) in the presence of tetraethylammonium bromide was employed for the reaction in aqueous m...

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Main Authors: Chutima Kuhakarn, Waraporn Panchan, Supanimit Chiampanichayakul, Natthapol Samakkanad, Manat Pohmakotr, Vichai Reutrakul, Thaworn Jaipetch
Other Authors: Mahidol University
Format: Article
Published: 2018
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Online Access:https://repository.li.mahidol.ac.th/handle/123456789/27385
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spelling th-mahidol.273852018-09-13T13:32:20Z 2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals Chutima Kuhakarn Waraporn Panchan Supanimit Chiampanichayakul Natthapol Samakkanad Manat Pohmakotr Vichai Reutrakul Thaworn Jaipetch Mahidol University Chemical Engineering Chemistry A simple and efficient procedure has been developed for the oxidation of cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters, respectively. 2-Iodoxybenzoic acid (IBX) in the presence of tetraethylammonium bromide was employed for the reaction in aqueous media. The salient features of the protocol include short reaction time, environmentally benign reagents and solvent, and moderate to high yields. © Georg Thieme Verlag Stuttgart. 2018-09-13T06:29:54Z 2018-09-13T06:29:54Z 2009-03-01 Article Synthesis. No.6 (2009), 929-934 10.1055/s-0028-1087986 1437210X 00397881 2-s2.0-67649425370 https://repository.li.mahidol.ac.th/handle/123456789/27385 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=67649425370&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemical Engineering
Chemistry
spellingShingle Chemical Engineering
Chemistry
Chutima Kuhakarn
Waraporn Panchan
Supanimit Chiampanichayakul
Natthapol Samakkanad
Manat Pohmakotr
Vichai Reutrakul
Thaworn Jaipetch
2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals
description A simple and efficient procedure has been developed for the oxidation of cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters, respectively. 2-Iodoxybenzoic acid (IBX) in the presence of tetraethylammonium bromide was employed for the reaction in aqueous media. The salient features of the protocol include short reaction time, environmentally benign reagents and solvent, and moderate to high yields. © Georg Thieme Verlag Stuttgart.
author2 Mahidol University
author_facet Mahidol University
Chutima Kuhakarn
Waraporn Panchan
Supanimit Chiampanichayakul
Natthapol Samakkanad
Manat Pohmakotr
Vichai Reutrakul
Thaworn Jaipetch
format Article
author Chutima Kuhakarn
Waraporn Panchan
Supanimit Chiampanichayakul
Natthapol Samakkanad
Manat Pohmakotr
Vichai Reutrakul
Thaworn Jaipetch
author_sort Chutima Kuhakarn
title 2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals
title_short 2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals
title_full 2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals
title_fullStr 2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals
title_full_unstemmed 2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals
title_sort 2-iodoxybenzoic acid/tetraethylammonium bromide/water: an efficient combination for oxidative cleavage of acetals
publishDate 2018
url https://repository.li.mahidol.ac.th/handle/123456789/27385
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