PhI(OAc)<inf>2</inf> mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones

PhI(OAc)<inf>2</inf> mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones

© The Royal Society of Chemistry 2015. A highly efficient metal-free decarboxylative sulfonylation protocol for the preparation of (E)-vinyl sulfones from of β-aryl-α,β-unsaturated carboxylic acids using sodium sulfinates and (diacetoxyiodo)benzene (PhI(OAc)<inf>2</inf>) was developed. T...

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Main Authors: Praewpan Katrun, Sornsiri Hlekhlai, Jatuporn Meesin, Manat Pohmakotr, Vichai Reutrakul, Thaworn Jaipetch, Darunee Soorukram, Chutima Kuhakarn
Other Authors: Mahidol University
Format: Article
Published: 2018
Subjects:
Biochemistry, Genetics and Molecular Biology
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/35464
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spelling th-mahidol.354642018-11-23T16:57:07Z PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones Praewpan Katrun Sornsiri Hlekhlai Jatuporn Meesin Manat Pohmakotr Vichai Reutrakul Thaworn Jaipetch Darunee Soorukram Chutima Kuhakarn Mahidol University Biochemistry, Genetics and Molecular Biology Chemistry © The Royal Society of Chemistry 2015. A highly efficient metal-free decarboxylative sulfonylation protocol for the preparation of (E)-vinyl sulfones from of β-aryl-α,β-unsaturated carboxylic acids using sodium sulfinates and (diacetoxyiodo)benzene (PhI(OAc)<inf>2</inf>) was developed. This strategy offers a simple and expedient synthesis of (E)-vinyl sulfones bearing a wide variety of functional groups. A radical-based pathway has been proposed for this decarboxylative sulfonylation reaction. 2018-11-23T09:43:46Z 2018-11-23T09:43:46Z 2015-04-28 Article Organic and Biomolecular Chemistry. Vol.13, No.16 (2015), 4785-4794 10.1039/c5ob00417a 14770520 2-s2.0-84927615292 https://repository.li.mahidol.ac.th/handle/123456789/35464 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84927615292&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Biochemistry, Genetics and Molecular Biology
Chemistry
spellingShingle Biochemistry, Genetics and Molecular Biology
Chemistry
Praewpan Katrun
Sornsiri Hlekhlai
Jatuporn Meesin
Manat Pohmakotr
Vichai Reutrakul
Thaworn Jaipetch
Darunee Soorukram
Chutima Kuhakarn
PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones
description © The Royal Society of Chemistry 2015. A highly efficient metal-free decarboxylative sulfonylation protocol for the preparation of (E)-vinyl sulfones from of β-aryl-α,β-unsaturated carboxylic acids using sodium sulfinates and (diacetoxyiodo)benzene (PhI(OAc)<inf>2</inf>) was developed. This strategy offers a simple and expedient synthesis of (E)-vinyl sulfones bearing a wide variety of functional groups. A radical-based pathway has been proposed for this decarboxylative sulfonylation reaction.
author2 Mahidol University
author_facet Mahidol University
Praewpan Katrun
Sornsiri Hlekhlai
Jatuporn Meesin
Manat Pohmakotr
Vichai Reutrakul
Thaworn Jaipetch
Darunee Soorukram
Chutima Kuhakarn
format Article
author Praewpan Katrun
Sornsiri Hlekhlai
Jatuporn Meesin
Manat Pohmakotr
Vichai Reutrakul
Thaworn Jaipetch
Darunee Soorukram
Chutima Kuhakarn
author_sort Praewpan Katrun
title PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones
title_short PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones
title_full PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones
title_fullStr PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones
title_full_unstemmed PhI(OAc)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: A synthesis of (E)-vinyl sulfones
title_sort phi(oac)&lt;inf&gt;2&lt;/inf&gt; mediated decarboxylative sulfonylation of β-aryl-α,β-unsaturated carboxylic acids: a synthesis of (e)-vinyl sulfones
publishDate 2018
url https://repository.li.mahidol.ac.th/handle/123456789/35464
_version_ 1763488049037049856

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