Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

© The Royal Society of Chemistry 2015. The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the obser...

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Main Authors:	Sangita Karanjit, Atchaleeya Jinasan, Ekasith Samsook, Raghu N. Dhital, Kenichi Motomiya, Yoshinori Sato, Kazuyuki Tohji, Hidehiro Sakurai
Other Authors:	Osaka University
Format:	Article
Published:	2018
Subjects:	Chemical Engineering Chemistry Materials Science
Online Access:	https://repository.li.mahidol.ac.th/handle/123456789/35695
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Institution:	Mahidol University

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spelling	th-mahidol.356952018-11-23T17:23:04Z Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides Sangita Karanjit Atchaleeya Jinasan Ekasith Samsook Raghu N. Dhital Kenichi Motomiya Yoshinori Sato Kazuyuki Tohji Hidehiro Sakurai Osaka University Mahidol University Tohoku University Interdisciplinary Cluster for Cutting Edge Research Japan Science and Technology Agency Shinshu University Chemical Engineering Chemistry Materials Science © The Royal Society of Chemistry 2015. The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by in situ generated Au-rich bimetallic Au/Pd nanoclusters. 2018-11-23T09:53:45Z 2018-11-23T09:53:45Z 2015-08-18 Article Chemical Communications. Vol.51, No.64 (2015), 12724-12727 10.1039/c5cc04432d 1364548X 13597345 2-s2.0-84938247919 https://repository.li.mahidol.ac.th/handle/123456789/35695 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84938247919&origin=inward
institution	Mahidol University
building	Mahidol University Library
continent	Asia
country	Thailand Thailand
content_provider	Mahidol University Library
collection	Mahidol University Institutional Repository
topic	Chemical Engineering Chemistry Materials Science
spellingShingle	Chemical Engineering Chemistry Materials Science Sangita Karanjit Atchaleeya Jinasan Ekasith Samsook Raghu N. Dhital Kenichi Motomiya Yoshinori Sato Kazuyuki Tohji Hidehiro Sakurai Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
description	© The Royal Society of Chemistry 2015. The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by in situ generated Au-rich bimetallic Au/Pd nanoclusters.
author2	Osaka University
author_facet	Osaka University Sangita Karanjit Atchaleeya Jinasan Ekasith Samsook Raghu N. Dhital Kenichi Motomiya Yoshinori Sato Kazuyuki Tohji Hidehiro Sakurai
format	Article
author	Sangita Karanjit Atchaleeya Jinasan Ekasith Samsook Raghu N. Dhital Kenichi Motomiya Yoshinori Sato Kazuyuki Tohji Hidehiro Sakurai
author_sort	Sangita Karanjit
title	Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
title_short	Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
title_full	Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
title_fullStr	Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
title_full_unstemmed	Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
title_sort	significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
publishDate	2018
url	https://repository.li.mahidol.ac.th/handle/123456789/35695
_version_	1763491436477546496

Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

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