One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations
© 2015, Springer-Verlag Berlin Heidelberg. Hybrid hollow latex (HL) particles possessing poly(styrene-co-acrylic acid) (P(St/AA)) as the inner shell, poly(divinyl benzene) (PDVB) as the outer shell, and silica nanoparticles (SiNPs) as the stabilizer were conveniently prepared via the combined Picker...
Saved in:
Main Authors: | , , , |
---|---|
Other Authors: | |
Format: | Article |
Published: |
2018
|
Subjects: | |
Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/35703 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Mahidol University |
id |
th-mahidol.35703 |
---|---|
record_format |
dspace |
spelling |
th-mahidol.357032018-11-23T17:23:31Z One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations Jirawat Narongthong Sukanya Nuasaen Teeraporn Suteewong Pramuan Tangboriboonrat Mahidol University King Mongkut's Institute of Technology Ladkrabang Chemical Engineering Chemistry Materials Science © 2015, Springer-Verlag Berlin Heidelberg. Hybrid hollow latex (HL) particles possessing poly(styrene-co-acrylic acid) (P(St/AA)) as the inner shell, poly(divinyl benzene) (PDVB) as the outer shell, and silica nanoparticles (SiNPs) as the stabilizer were conveniently prepared via the combined Pickering and seeded emulsion polymerizations. P(St/AA) particles (435 nm) were used as seeds, DVB as a swollen and crosslink monomer, 2,2′-azobis(2-methylpropionamidine) dihydrochloride as initiator, and SiNPs as Pickering stabilizer. Without core removal, solvent evaporation, and surface modification steps, the spherical, monodisperse, and non-collapsed HL-SiNPs particles (722 nm) with double shell polymer layer and a large void cavity (400 nm) were obtained. The presence of large cavity and double shell may enable these hybrid HL-SiNPs particles to be used as lightweight filler and/or white pigment in coatings. 2018-11-23T09:54:09Z 2018-11-23T09:54:09Z 2015-04-01 Article Colloid and Polymer Science. Vol.293, No.4 (2015), 1269-1274 10.1007/s00396-015-3522-y 14351536 0303402X 2-s2.0-84939960537 https://repository.li.mahidol.ac.th/handle/123456789/35703 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84939960537&origin=inward |
institution |
Mahidol University |
building |
Mahidol University Library |
continent |
Asia |
country |
Thailand Thailand |
content_provider |
Mahidol University Library |
collection |
Mahidol University Institutional Repository |
topic |
Chemical Engineering Chemistry Materials Science |
spellingShingle |
Chemical Engineering Chemistry Materials Science Jirawat Narongthong Sukanya Nuasaen Teeraporn Suteewong Pramuan Tangboriboonrat One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations |
description |
© 2015, Springer-Verlag Berlin Heidelberg. Hybrid hollow latex (HL) particles possessing poly(styrene-co-acrylic acid) (P(St/AA)) as the inner shell, poly(divinyl benzene) (PDVB) as the outer shell, and silica nanoparticles (SiNPs) as the stabilizer were conveniently prepared via the combined Pickering and seeded emulsion polymerizations. P(St/AA) particles (435 nm) were used as seeds, DVB as a swollen and crosslink monomer, 2,2′-azobis(2-methylpropionamidine) dihydrochloride as initiator, and SiNPs as Pickering stabilizer. Without core removal, solvent evaporation, and surface modification steps, the spherical, monodisperse, and non-collapsed HL-SiNPs particles (722 nm) with double shell polymer layer and a large void cavity (400 nm) were obtained. The presence of large cavity and double shell may enable these hybrid HL-SiNPs particles to be used as lightweight filler and/or white pigment in coatings. |
author2 |
Mahidol University |
author_facet |
Mahidol University Jirawat Narongthong Sukanya Nuasaen Teeraporn Suteewong Pramuan Tangboriboonrat |
format |
Article |
author |
Jirawat Narongthong Sukanya Nuasaen Teeraporn Suteewong Pramuan Tangboriboonrat |
author_sort |
Jirawat Narongthong |
title |
One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations |
title_short |
One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations |
title_full |
One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations |
title_fullStr |
One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations |
title_full_unstemmed |
One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations |
title_sort |
one-pot synthesis of organic-inorganic hybrid hollow latex particles via pickering and seeded emulsion polymerizations |
publishDate |
2018 |
url |
https://repository.li.mahidol.ac.th/handle/123456789/35703 |
_version_ |
1763492439562125312 |