Interphase transfer of plasticizer between immiscible rubbers
© 2015 Elsevier Ltd.All rights reserved. Interphase transfer of di-2-ethylhexyl adipate (DOA) between ethylene-propylene copolymer (EPR) and polyisobutylene (PIB) in the laminated sheets was studied. It was found that the amount of DOA in each phase is determined by the ambient temperature. DOA move...
Saved in:
| Main Authors: | , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Published: |
2018
|
| Subjects: | |
| Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/35731 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Mahidol University |
| id |
th-mahidol.35731 |
|---|---|
| record_format |
dspace |
| spelling |
th-mahidol.357312018-11-23T17:23:00Z Interphase transfer of plasticizer between immiscible rubbers Nawaphorn Kuhakongkiat Viyada Wachteng Shogo Nobukawa Masayuki Yamaguchi Japan Advanced Institute of Science and Technology Mahidol University Chemistry Materials Science © 2015 Elsevier Ltd.All rights reserved. Interphase transfer of di-2-ethylhexyl adipate (DOA) between ethylene-propylene copolymer (EPR) and polyisobutylene (PIB) in the laminated sheets was studied. It was found that the amount of DOA in each phase is determined by the ambient temperature. DOA moved to EPR from PIB at -20 °C and vice versa at 40 °C, when the DOA content before lamination was 10 phr. This is attributed to the change of interaction parameters between DOA and each rubber as a function of temperature. Because of the DOA transfer, the glass transition temperature of each rubber phase changes with the ambient temperature. The phenomenon can be applicable to an all-season tire, when a matrix polymer contains more plasticizer at low temperature and vice versa in a blend with sea-island structure. 2018-11-23T09:55:40Z 2018-11-23T09:55:40Z 2015-11-05 Article Polymer. Vol.78, (2015), 208-211 10.1016/j.polymer.2015.09.079 00323861 2-s2.0-84944050079 https://repository.li.mahidol.ac.th/handle/123456789/35731 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84944050079&origin=inward |
| institution |
Mahidol University |
| building |
Mahidol University Library |
| continent |
Asia |
| country |
Thailand Thailand |
| content_provider |
Mahidol University Library |
| collection |
Mahidol University Institutional Repository |
| topic |
Chemistry Materials Science |
| spellingShingle |
Chemistry Materials Science Nawaphorn Kuhakongkiat Viyada Wachteng Shogo Nobukawa Masayuki Yamaguchi Interphase transfer of plasticizer between immiscible rubbers |
| description |
© 2015 Elsevier Ltd.All rights reserved. Interphase transfer of di-2-ethylhexyl adipate (DOA) between ethylene-propylene copolymer (EPR) and polyisobutylene (PIB) in the laminated sheets was studied. It was found that the amount of DOA in each phase is determined by the ambient temperature. DOA moved to EPR from PIB at -20 °C and vice versa at 40 °C, when the DOA content before lamination was 10 phr. This is attributed to the change of interaction parameters between DOA and each rubber as a function of temperature. Because of the DOA transfer, the glass transition temperature of each rubber phase changes with the ambient temperature. The phenomenon can be applicable to an all-season tire, when a matrix polymer contains more plasticizer at low temperature and vice versa in a blend with sea-island structure. |
| author2 |
Japan Advanced Institute of Science and Technology |
| author_facet |
Japan Advanced Institute of Science and Technology Nawaphorn Kuhakongkiat Viyada Wachteng Shogo Nobukawa Masayuki Yamaguchi |
| format |
Article |
| author |
Nawaphorn Kuhakongkiat Viyada Wachteng Shogo Nobukawa Masayuki Yamaguchi |
| author_sort |
Nawaphorn Kuhakongkiat |
| title |
Interphase transfer of plasticizer between immiscible rubbers |
| title_short |
Interphase transfer of plasticizer between immiscible rubbers |
| title_full |
Interphase transfer of plasticizer between immiscible rubbers |
| title_fullStr |
Interphase transfer of plasticizer between immiscible rubbers |
| title_full_unstemmed |
Interphase transfer of plasticizer between immiscible rubbers |
| title_sort |
interphase transfer of plasticizer between immiscible rubbers |
| publishDate |
2018 |
| url |
https://repository.li.mahidol.ac.th/handle/123456789/35731 |
| _version_ |
1763487200023937024 |