Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains

Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains

© 2016 The Royal Society of Chemistry. Herein we report the synthesis and investigation of the properties of two tris-cyclometalated luminescent iridium complexes. These complexes are the simple derivatives of fac-[Ir(ppy)3] bearing amino alkyl groups on one of the phenylpyridine rings. The complexe...

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Main Authors: A. Sansee, S. Meksawangwong, K. Chainok, K. J. Franz, M. Gál, L. O. Pålsson, W. Puniyan, R. Traiphol, R. Pal, F. Kielar
Other Authors: Naresuan University
Format: Article
Published: 2018
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/43439
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spelling th-mahidol.434392019-03-14T15:04:30Z Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains A. Sansee S. Meksawangwong K. Chainok K. J. Franz M. Gál L. O. Pålsson W. Puniyan R. Traiphol R. Pal F. Kielar Naresuan University Thammasat University Duke University Slovak University of Technology in Bratislava University of Durham Naresuan Univesity Mahidol University Chemistry © 2016 The Royal Society of Chemistry. Herein we report the synthesis and investigation of the properties of two tris-cyclometalated luminescent iridium complexes. These complexes are the simple derivatives of fac-[Ir(ppy)3] bearing amino alkyl groups on one of the phenylpyridine rings. The complexes are highly emissive and exhibit structured emission peaks in aqueous solution while having only broad unstructured emission in organic solvents. The complexes have been shown to be taken up by NIH-3T3 and PC3 cells, where they localize in the lysosomes and remain emissive with lifetimes in the microsecond domain. 2018-12-11T02:36:46Z 2019-03-14T08:04:30Z 2018-12-11T02:36:46Z 2019-03-14T08:04:30Z 2016-01-01 Article Dalton Transactions. Vol.45, No.43 (2016), 17420-17430 10.1039/c6dt02776h 14779234 14779226 2-s2.0-84994663253 https://repository.li.mahidol.ac.th/handle/123456789/43439 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84994663253&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemistry
spellingShingle Chemistry
A. Sansee
S. Meksawangwong
K. Chainok
K. J. Franz
M. Gál
L. O. Pålsson
W. Puniyan
R. Traiphol
R. Pal
F. Kielar
Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
description © 2016 The Royal Society of Chemistry. Herein we report the synthesis and investigation of the properties of two tris-cyclometalated luminescent iridium complexes. These complexes are the simple derivatives of fac-[Ir(ppy)3] bearing amino alkyl groups on one of the phenylpyridine rings. The complexes are highly emissive and exhibit structured emission peaks in aqueous solution while having only broad unstructured emission in organic solvents. The complexes have been shown to be taken up by NIH-3T3 and PC3 cells, where they localize in the lysosomes and remain emissive with lifetimes in the microsecond domain.
author2 Naresuan University
author_facet Naresuan University
A. Sansee
S. Meksawangwong
K. Chainok
K. J. Franz
M. Gál
L. O. Pålsson
W. Puniyan
R. Traiphol
R. Pal
F. Kielar
format Article
author A. Sansee
S. Meksawangwong
K. Chainok
K. J. Franz
M. Gál
L. O. Pålsson
W. Puniyan
R. Traiphol
R. Pal
F. Kielar
author_sort A. Sansee
title Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
title_short Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
title_full Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
title_fullStr Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
title_full_unstemmed Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
title_sort novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
publishDate 2018
url https://repository.li.mahidol.ac.th/handle/123456789/43439
_version_ 1763494093129777152

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