Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes

Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes

© The Royal Society of Chemistry. Diverse 2-sulfonyl- and 2-thiocyanato-3-substituted quinolines were synthesized from o-alkynylisocyanobenzenes by nucleophilic addition of the respective sulfinate sodium salts and ammonium thiocyanate to the isocyanide moiety followed by cyclization. The salient fe...

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Main Authors: Onnicha Khaikate, Jatuporn Meesin, Manat Pohmakotr, Vichai Reutrakul, Pawaret Leowanawat, Darunee Soorukram, Chutima Kuhakarn
Other Authors: Mahidol University
Format: Article
Published: 2019
Subjects:
Biochemistry, Genetics and Molecular Biology
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/45272
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spelling th-mahidol.452722019-08-23T17:51:54Z Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes Onnicha Khaikate Jatuporn Meesin Manat Pohmakotr Vichai Reutrakul Pawaret Leowanawat Darunee Soorukram Chutima Kuhakarn Mahidol University Biochemistry, Genetics and Molecular Biology Chemistry © The Royal Society of Chemistry. Diverse 2-sulfonyl- and 2-thiocyanato-3-substituted quinolines were synthesized from o-alkynylisocyanobenzenes by nucleophilic addition of the respective sulfinate sodium salts and ammonium thiocyanate to the isocyanide moiety followed by cyclization. The salient features of the methodology include metal-free, ambient temperature and mild reaction conditions, ease of reagent handling, and broad functional group tolerance. 2019-08-23T10:38:30Z 2019-08-23T10:38:30Z 2018-01-01 Article Organic and Biomolecular Chemistry. Vol.16, No.44 (2018), 8553-8558 10.1039/C8OB02338G 14770520 2-s2.0-85056520766 https://repository.li.mahidol.ac.th/handle/123456789/45272 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85056520766&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Biochemistry, Genetics and Molecular Biology
Chemistry
spellingShingle Biochemistry, Genetics and Molecular Biology
Chemistry
Onnicha Khaikate
Jatuporn Meesin
Manat Pohmakotr
Vichai Reutrakul
Pawaret Leowanawat
Darunee Soorukram
Chutima Kuhakarn
Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
description © The Royal Society of Chemistry. Diverse 2-sulfonyl- and 2-thiocyanato-3-substituted quinolines were synthesized from o-alkynylisocyanobenzenes by nucleophilic addition of the respective sulfinate sodium salts and ammonium thiocyanate to the isocyanide moiety followed by cyclization. The salient features of the methodology include metal-free, ambient temperature and mild reaction conditions, ease of reagent handling, and broad functional group tolerance.
author2 Mahidol University
author_facet Mahidol University
Onnicha Khaikate
Jatuporn Meesin
Manat Pohmakotr
Vichai Reutrakul
Pawaret Leowanawat
Darunee Soorukram
Chutima Kuhakarn
format Article
author Onnicha Khaikate
Jatuporn Meesin
Manat Pohmakotr
Vichai Reutrakul
Pawaret Leowanawat
Darunee Soorukram
Chutima Kuhakarn
author_sort Onnicha Khaikate
title Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
title_short Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
title_full Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
title_fullStr Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
title_full_unstemmed Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
title_sort sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes
publishDate 2019
url https://repository.li.mahidol.ac.th/handle/123456789/45272
_version_ 1763491857739808768

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