Self-assembled Cu(II) cluster from aerobic oxidation of Cu(I)Br with tris(triazolyl)methanol
© 2019 Elsevier B.V. Treatment of tris(4-benzyl-1,2,3-triazolyl)methanol (Htbtm) with CuIBr in refluxed CH2Cl2 under aerobic conditions afforded the hexanuclear CuII complexes with the formula Cu6(µ3-O⋯H⋯O-µ3)(µ-tbtm-к3-O,N3,N3′)3(µ-Br)6. The crystal structure reveals two Cu3(µ-Br)3(µ3-O) units link...
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Main Authors: | , , , , , |
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Format: | Article |
Published: |
2020
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Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/50574 |
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Institution: | Mahidol University |