Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers

Cross-linked siloxane/silsesquioxane-based elastomers were easily prepared in 15 min via the anionic ring-opening polymerization of cyclotetrasiloxane (D4) and a polyhedral oligomeric silsesquioxane, using K2CO3 as a catalytic base in dimethylformamide at 70 °C. The resulting silicone elastomers hav...

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Main Author: Wannasiri C.
Other Authors: Mahidol University
Format: Article
Published: 2023
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Online Access:https://repository.li.mahidol.ac.th/handle/123456789/81764
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spelling th-mahidol.817642023-05-19T14:38:42Z Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers Wannasiri C. Mahidol University Chemistry Cross-linked siloxane/silsesquioxane-based elastomers were easily prepared in 15 min via the anionic ring-opening polymerization of cyclotetrasiloxane (D4) and a polyhedral oligomeric silsesquioxane, using K2CO3 as a catalytic base in dimethylformamide at 70 °C. The resulting silicone elastomers have high mechanical strength, good thermal stability, and good superhydrophobic properties. 2023-05-19T07:38:42Z 2023-05-19T07:38:42Z 2023-01-01 Article Chemical Communications (2023) 10.1039/d2cc06974a 1364548X 13597345 37070655 2-s2.0-85153034253 https://repository.li.mahidol.ac.th/handle/123456789/81764 SCOPUS
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemistry
spellingShingle Chemistry
Wannasiri C.
Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
description Cross-linked siloxane/silsesquioxane-based elastomers were easily prepared in 15 min via the anionic ring-opening polymerization of cyclotetrasiloxane (D4) and a polyhedral oligomeric silsesquioxane, using K2CO3 as a catalytic base in dimethylformamide at 70 °C. The resulting silicone elastomers have high mechanical strength, good thermal stability, and good superhydrophobic properties.
author2 Mahidol University
author_facet Mahidol University
Wannasiri C.
format Article
author Wannasiri C.
author_sort Wannasiri C.
title Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
title_short Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
title_full Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
title_fullStr Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
title_full_unstemmed Ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
title_sort ultrafast synthesis of silicone elastomers using silsesquioxane cages as crosslinkers
publishDate 2023
url https://repository.li.mahidol.ac.th/handle/123456789/81764
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