SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID
Asymmetric catalysis is a type of catalysis in which a chiral catalyst directs the formation of a chiral <br /> <br /> compound that continue to develop today. Organocatalyst is widely used due to its easy and <br /> <br /> environmentally friendly process. For example, BINOL...
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id-itb.:280822018-09-17T10:59:36ZSYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID SEPTIARINI PRATIWI (NIM:10514052), INTAN Indonesia Final Project INSTITUT TEKNOLOGI BANDUNG https://digilib.itb.ac.id/gdl/view/28082 Asymmetric catalysis is a type of catalysis in which a chiral catalyst directs the formation of a chiral <br /> <br /> compound that continue to develop today. Organocatalyst is widely used due to its easy and <br /> <br /> environmentally friendly process. For example, BINOL derived chiral phosphoric acid. The <br /> <br /> application of BINOL-phosphoric acid is used as a catalyst and resolving agent. Separation of racemic <br /> <br /> compounds from BINOL-phosphoric acid was carried out by diastereomeric salt formation and <br /> <br /> optical rotation was produced at <br /> <br /> =+2o (c=1, CHCl3) with %ee 0,3% and <br /> <br /> = -14o (c=1, <br /> <br /> CHCl3) with %ee 2%. All products was characterized by spectroscopy data including 1H-NMR and <br /> <br /> 13C-NMR. text |
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Asymmetric catalysis is a type of catalysis in which a chiral catalyst directs the formation of a chiral <br />
<br />
compound that continue to develop today. Organocatalyst is widely used due to its easy and <br />
<br />
environmentally friendly process. For example, BINOL derived chiral phosphoric acid. The <br />
<br />
application of BINOL-phosphoric acid is used as a catalyst and resolving agent. Separation of racemic <br />
<br />
compounds from BINOL-phosphoric acid was carried out by diastereomeric salt formation and <br />
<br />
optical rotation was produced at <br />
<br />
=+2o (c=1, CHCl3) with %ee 0,3% and <br />
<br />
= -14o (c=1, <br />
<br />
CHCl3) with %ee 2%. All products was characterized by spectroscopy data including 1H-NMR and <br />
<br />
13C-NMR. |
| format |
Final Project |
| author |
SEPTIARINI PRATIWI (NIM:10514052), INTAN |
| spellingShingle |
SEPTIARINI PRATIWI (NIM:10514052), INTAN SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID |
| author_facet |
SEPTIARINI PRATIWI (NIM:10514052), INTAN |
| author_sort |
SEPTIARINI PRATIWI (NIM:10514052), INTAN |
| title |
SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID |
| title_short |
SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID |
| title_full |
SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID |
| title_fullStr |
SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID |
| title_full_unstemmed |
SYNTHESIS OF ENANTIOMER BINOL-PHOSPHORIC ACID |
| title_sort |
synthesis of enantiomer binol-phosphoric acid |
| url |
https://digilib.itb.ac.id/gdl/view/28082 |
| _version_ |
1822021578456563712 |