Possible origin of electronic effects in Rh(I)-catalyzed enantioselective hydrogenation

Reducing the electron density of ligands switches the regioselectivity of Rh(I)-catalyzed hydrometalation. A reversal of the sense of chiral induction was also observed when chiral ligands are electronically tuned in the same manner. The combined data provide an alternative rationale for the electro...

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Bibliographic Details
Main Authors: Wu, Hai-Chen, Abd Hamid, Shafida, Yu, Jin-Quan, Spencer, Jonathan B
Format: Article
Language:English
Published: American Chemical Society 2009
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Online Access:http://irep.iium.edu.my/10332/1/sw-2.pdf
http://irep.iium.edu.my/10332/
http://pubs.acs.org/doi/abs/10.1021/ja903089f
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Institution: Universiti Islam Antarabangsa Malaysia
Language: English