(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate
The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/12001/ |
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| Institution: | Universiti Malaya |
| Summary: | The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. |
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