(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate
The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate...
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2010
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my.um.eprints.120012019-01-30T08:18:27Z http://eprints.um.edu.my/12001/ (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. Q Science (General) The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. International Union of Crystallography 2010 Article PeerReviewed Zhang, Kou-Lin and Diao, Guo-Wang and Ng, S.W. (2010) (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1421-U783. ISSN 1600-5368 |
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Q Science (General) Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| description |
The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. |
| format |
Article |
| author |
Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. |
| author_facet |
Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. |
| author_sort |
Zhang, Kou-Lin |
| title |
(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_short |
(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_full |
(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_fullStr |
(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_full_unstemmed |
(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_sort |
(5-aminoisophthalato-kappa n)triaqua(1,10-phenanthroline-kappa n-2,n `)cobalt(ii) trihydrate |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/12001/ |
| _version_ |
1643689194150690816 |