Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chl...
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| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/14652/ |
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| Institution: | Universiti Malaya |
| Summary: | The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C-H center dot center dot center dot O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4). |
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