Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate

• Main Authors: Roy, T.G., Hazari, S.K.S., Barua, K.K., Ng, S.W., Tiekink, E.R.T.
• Format: Article
• Published: International Union of Crystallography 2011
• Subjects: QC Physics
• Online Access: http://eprints.um.edu.my/14652/
• Institution: Universiti Malaya

The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chl...