[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060...
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| Main Authors: | , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/14777/ |
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| Institution: | Universiti Malaya |
| Summary: | The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. In the crystal structure, molecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H center dot center dot center dot pi. |
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