[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060...

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Main Authors: Tadbuppa, P.P., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/14777/
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Institution: Universiti Malaya
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spelling my.um.eprints.147772019-01-30T09:02:22Z http://eprints.um.edu.my/14777/ [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) Tadbuppa, P.P. Tiekink, E.R.T. QC Physics The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. In the crystal structure, molecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H center dot center dot center dot pi. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M421-U800. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Tadbuppa, P.P.
Tiekink, E.R.T.
[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
description The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. In the crystal structure, molecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H center dot center dot center dot pi.
format Article
author Tadbuppa, P.P.
Tiekink, E.R.T.
author_facet Tadbuppa, P.P.
Tiekink, E.R.T.
author_sort Tadbuppa, P.P.
title [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
title_short [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
title_full [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
title_fullStr [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
title_full_unstemmed [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
title_sort [(z)-o-isopropyl n-(m-tolyl) thiocarbamato-kappa s](tricyclohexylphosphine-kappa p)gold(i)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/14777/
_version_ 1643689898269474816

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