Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor

A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogene...

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Main Authors:	Wong, S.P., Gan, C.Y., Lim, K.H., Ting, K.N., Low, Y.Y., Kam, T.S.
Format:	Article
Published:	American Chemical Society 2015
Subjects:	Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General)
Online Access:	http://eprints.um.edu.my/19443/ http://dx.doi.org/10.1021/acs.orglett.5b01757
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Institution:	Universiti Malaya

id	my.um.eprints.19443
record_format	eprints
spelling	my.um.eprints.194432018-09-28T02:17:44Z http://eprints.um.edu.my/19443/ Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S. Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General) A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogenetic pathway from a pericine precursor is presented. American Chemical Society 2015 Article PeerReviewed Wong, S.P. and Gan, C.Y. and Lim, K.H. and Ting, K.N. and Low, Y.Y. and Kam, T.S. (2015) Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor. Organic Letters, 17 (14). pp. 3628-3631. ISSN 1523-7060 http://dx.doi.org/10.1021/acs.orglett.5b01757 doi:10.1021/acs.orglett.5b01757
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
topic	Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General)
spellingShingle	Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General) Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S. Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
description	A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogenetic pathway from a pericine precursor is presented.
format	Article
author	Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S.
author_facet	Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S.
author_sort	Wong, S.P.
title	Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
title_short	Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
title_full	Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
title_fullStr	Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
title_full_unstemmed	Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
title_sort	arboridinine, a pentacyclic indole alkaloid with a new cage carbon–nitrogen skeleton derived from a pericine precursor
publisher	American Chemical Society
publishDate	2015
url	http://eprints.um.edu.my/19443/ http://dx.doi.org/10.1021/acs.orglett.5b01757
_version_	1643690990040514560

Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor

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