Bis(quinolin-8-olato-κ2N,O)lead(II)
The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in th...
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| Main Authors: | , , |
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| 格式: | Article |
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International Union of Crystallography
2005
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| 主題: | |
| 在線閱讀: | http://eprints.um.edu.my/25280/ https://doi.org/10.1107/S1600536805011852 |
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| 機構: | Universiti Malaya |
| 總結: | The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in the asymmetric unit with similar geometry around the Pb atoms, which have a pseudo-pentagonal-bipyramidal coordination with one of the axial positions occupied by the Pb lone pair. Some distances involving the Pb atoms are significantly different between the two molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. |
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