Bis(quinolin-8-olato-κ2N,O)lead(II)
The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in th...
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International Union of Crystallography
2005
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my.um.eprints.252802020-08-06T06:21:49Z http://eprints.um.edu.my/25280/ Bis(quinolin-8-olato-κ2N,O)lead(II) Zhu, Li-Hong Zeng, Ming-Hua Ng, Seik Weng Q Science (General) QD Chemistry The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in the asymmetric unit with similar geometry around the Pb atoms, which have a pseudo-pentagonal-bipyramidal coordination with one of the axial positions occupied by the Pb lone pair. Some distances involving the Pb atoms are significantly different between the two molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. International Union of Crystallography 2005 Article PeerReviewed Zhu, Li-Hong and Zeng, Ming-Hua and Ng, Seik Weng (2005) Bis(quinolin-8-olato-κ2N,O)lead(II). Acta Crystallographica Section E: Structure Reports Online, 61 (6). m1082-m1084. ISSN 1600-5368 https://doi.org/10.1107/S1600536805011852 doi:10.1107/S1600536805011852 |
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Q Science (General) QD Chemistry Zhu, Li-Hong Zeng, Ming-Hua Ng, Seik Weng Bis(quinolin-8-olato-κ2N,O)lead(II) |
| description |
The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in the asymmetric unit with similar geometry around the Pb atoms, which have a pseudo-pentagonal-bipyramidal coordination with one of the axial positions occupied by the Pb lone pair. Some distances involving the Pb atoms are significantly different between the two molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| format |
Article |
| author |
Zhu, Li-Hong Zeng, Ming-Hua Ng, Seik Weng |
| author_facet |
Zhu, Li-Hong Zeng, Ming-Hua Ng, Seik Weng |
| author_sort |
Zhu, Li-Hong |
| title |
Bis(quinolin-8-olato-κ2N,O)lead(II) |
| title_short |
Bis(quinolin-8-olato-κ2N,O)lead(II) |
| title_full |
Bis(quinolin-8-olato-κ2N,O)lead(II) |
| title_fullStr |
Bis(quinolin-8-olato-κ2N,O)lead(II) |
| title_full_unstemmed |
Bis(quinolin-8-olato-κ2N,O)lead(II) |
| title_sort |
bis(quinolin-8-olato-κ2n,o)lead(ii) |
| publisher |
International Union of Crystallography |
| publishDate |
2005 |
| url |
http://eprints.um.edu.my/25280/ https://doi.org/10.1107/S1600536805011852 |
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1680857015521378304 |