{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)
In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot cen...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5207/1/Gwaram-2011-%7B2-Morpholino-N-_1-%28.pdf http://eprints.um.edu.my/5207/ http://journals.iucr.org/e/issues/2011/01/00/is2639/is2639bdy.html http://doi.org/10.1107/s1600536810050889 |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular pi-pi interaction occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) angstrom. |
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