{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)

• Main Authors: Gwaram, N.S., Ali, Hapipah Mohd, Khaledi, H., Hisham, N.A.I.
• Format: Article
• Language: English
• Published: International Union of Crystallography 2011
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/5207/1/Gwaram-2011-%7B2-Morpholino-N-_1-%28.pdf; http://eprints.um.edu.my/5207/; http://journals.iucr.org/e/issues/2011/01/00/is2639/is2639bdy.html; http://doi.org/10.1107/s1600536810050889
• Institution: Universiti Malaya

In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular pi-pi interaction occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) angstrom.