Aquachloridobis(2-{ 3-(morpholin-4-yl)propyl iminomethyl}phenolato)manganese(III) monohydrate
In the title compound, [Mn(C14H19N2O2)(2)Cl(H2O)]center dot H2O, the Mn-III atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the cryst...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5233/1/Hisham-2011-Aquachloridobis%282-%7B.pdf http://eprints.um.edu.my/5233/ http://scripts.iucr.org/cgi-bin/paper?S1600536811026493 |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | In the title compound, [Mn(C14H19N2O2)(2)Cl(H2O)]center dot H2O, the Mn-III atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the crystal, the complex molecules and the uncoordinated water molecules are connected via O-H center dot center dot center dot N, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network through C-H center dot center dot center dot O interactions. |
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