Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geom...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf http://eprints.um.edu.my/5327/ http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric
dinuclear cadmium(II) complex in which each two
metal ions are linked by a pair of thiocyanate N:S-bridges. Two
2-methylbenzimidazole N-atom donors and one terminal
thiocyanate N atom complete a highly distorted squarepyramidal
geometry around the Cd atom. In the crystal
structure, two N—H� � �S hydrogen-bonding interactions
occur, resulting in a three-dimensional polymeric structure.
The apical 2-methylbenzimidazole ring and its symmetryrelated
counterpart are arranged in an antiparallel manner
with a centroid–centroid separation of 3.6050 (14) A ° , indicative
of a �–� interaction. |
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