Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]

The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geom...

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Main Authors:	Ahaker, S., Mohd Ali, H., Khaledi, H.
Format:	Article
Language:	English
Published:	2010
Subjects:	QD Chemistry
Online Access:	http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf http://eprints.um.edu.my/5327/ http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf
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Institution:	Universiti Malaya
Language:	English

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spelling	my.um.eprints.53272013-04-01T04:33:41Z http://eprints.um.edu.my/5327/ Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] Ahaker, S. Mohd Ali, H. Khaledi, H. QD Chemistry The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geometry around the Cd atom. In the crystal structure, two N—H� � �S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetryrelated counterpart are arranged in an antiparallel manner with a centroid–centroid separation of 3.6050 (14) A ° , indicative of a �–� interaction. 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf Ahaker, S. and Mohd Ali, H. and Khaledi, H. (2010) Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). m1464-m1464. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Ahaker, S. Mohd Ali, H. Khaledi, H. Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
description	The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geometry around the Cd atom. In the crystal structure, two N—H� � �S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetryrelated counterpart are arranged in an antiparallel manner with a centroid–centroid separation of 3.6050 (14) A ° , indicative of a �–� interaction.
format	Article
author	Ahaker, S. Mohd Ali, H. Khaledi, H.
author_facet	Ahaker, S. Mohd Ali, H. Khaledi, H.
author_sort	Ahaker, S.
title	Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
title_short	Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
title_full	Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
title_fullStr	Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
title_full_unstemmed	Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
title_sort	di--thiocyanato-2n: s; 2s: n-bis [bis (2-methyl-1h-benzimidazole-n3)(thiocyanato-n) cadmium (ii)]
publishDate	2010
url	http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf http://eprints.um.edu.my/5327/ http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf
_version_	1643687546849329152

Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]

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