Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geom...
Saved in:
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
2010
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf http://eprints.um.edu.my/5327/ http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Universiti Malaya |
Language: | English |
id |
my.um.eprints.5327 |
---|---|
record_format |
eprints |
spelling |
my.um.eprints.53272013-04-01T04:33:41Z http://eprints.um.edu.my/5327/ Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] Ahaker, S. Mohd Ali, H. Khaledi, H. QD Chemistry The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geometry around the Cd atom. In the crystal structure, two N—H� � �S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetryrelated counterpart are arranged in an antiparallel manner with a centroid–centroid separation of 3.6050 (14) A ° , indicative of a �–� interaction. 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf Ahaker, S. and Mohd Ali, H. and Khaledi, H. (2010) Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). m1464-m1464. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf |
institution |
Universiti Malaya |
building |
UM Library |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Malaya |
content_source |
UM Research Repository |
url_provider |
http://eprints.um.edu.my/ |
language |
English |
topic |
QD Chemistry |
spellingShingle |
QD Chemistry Ahaker, S. Mohd Ali, H. Khaledi, H. Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
description |
The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric
dinuclear cadmium(II) complex in which each two
metal ions are linked by a pair of thiocyanate N:S-bridges. Two
2-methylbenzimidazole N-atom donors and one terminal
thiocyanate N atom complete a highly distorted squarepyramidal
geometry around the Cd atom. In the crystal
structure, two N—H� � �S hydrogen-bonding interactions
occur, resulting in a three-dimensional polymeric structure.
The apical 2-methylbenzimidazole ring and its symmetryrelated
counterpart are arranged in an antiparallel manner
with a centroid–centroid separation of 3.6050 (14) A ° , indicative
of a �–� interaction. |
format |
Article |
author |
Ahaker, S. Mohd Ali, H. Khaledi, H. |
author_facet |
Ahaker, S. Mohd Ali, H. Khaledi, H. |
author_sort |
Ahaker, S. |
title |
Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
title_short |
Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
title_full |
Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
title_fullStr |
Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
title_full_unstemmed |
Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
title_sort |
di--thiocyanato-2n: s; 2s: n-bis [bis (2-methyl-1h-benzimidazole-n3)(thiocyanato-n) cadmium (ii)] |
publishDate |
2010 |
url |
http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf http://eprints.um.edu.my/5327/ http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf |
_version_ |
1643687546849329152 |