S-Quinolin-2-ylmethyldithiocarbazate
In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf http://psasir.upm.edu.my/id/eprint/7516/ http://dx.doi.org/10.1107/S1600536807024609 |
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| Institution: | Universiti Putra Malaysia |
| Language: | English English |
| Summary: | In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05 (11)] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis Smethyldithiocarbazate and trans–cis S-benzyldithiocarbazate.This is due to the N—H N hydrogen bond that exists only in the cis–trans conformation found for the title compound. |
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