S-Quinolin-2-ylmethyldithiocarbazate
In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05...
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International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf http://psasir.upm.edu.my/id/eprint/7516/ http://dx.doi.org/10.1107/S1600536807024609 |
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my.upm.eprints.75162013-05-27T07:35:21Z http://psasir.upm.edu.my/id/eprint/7516/ S-Quinolin-2-ylmethyldithiocarbazate How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05 (11)] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis Smethyldithiocarbazate and trans–cis S-benzyldithiocarbazate.This is due to the N—H N hydrogen bond that exists only in the cis–trans conformation found for the title compound. International Union of Crystallography 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) S-Quinolin-2-ylmethyldithiocarbazate. Acta Crystallographica Section E: Structure Reports Online, 63 (7). pp. 3137-3138. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536807024609 10.1107/S1600536807024609 English |
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In the title compound, C11H11N2S2, there is an intramolecular N—H N [2.778 (2) A ° ] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1) with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)] and N—C—S [119.05 (11)] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis Smethyldithiocarbazate and trans–cis S-benzyldithiocarbazate.This is due to the N—H N hydrogen bond that exists only in the cis–trans conformation found for the title compound. |
| format |
Article |
| author |
How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| spellingShingle |
How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim S-Quinolin-2-ylmethyldithiocarbazate |
| author_facet |
How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort |
How, Fiona Ni Foong |
| title |
S-Quinolin-2-ylmethyldithiocarbazate |
| title_short |
S-Quinolin-2-ylmethyldithiocarbazate |
| title_full |
S-Quinolin-2-ylmethyldithiocarbazate |
| title_fullStr |
S-Quinolin-2-ylmethyldithiocarbazate |
| title_full_unstemmed |
S-Quinolin-2-ylmethyldithiocarbazate |
| title_sort |
s-quinolin-2-ylmethyldithiocarbazate |
| publisher |
International Union of Crystallography |
| publishDate |
2007 |
| url |
http://psasir.upm.edu.my/id/eprint/7516/1/S-Quinolin-2-ylmethyldithiocarbazate.pdf http://psasir.upm.edu.my/id/eprint/7516/ http://dx.doi.org/10.1107/S1600536807024609 |
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