Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)

Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)

The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned...

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Bibliographic Details
Main Authors: Md. Abdus, Salam, Md. Abu, Affan, Shamsuddin, Mustaffa, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science
Online Access:http://eprints.utm.my/id/eprint/28984/
http://dx.doi.org/10.1107/S1600536810014443
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Institution: Universiti Teknologi Malaysia
Description
Summary:The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].

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