Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)

Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)

The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned...

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Main Authors: Md. Abdus, Salam, Md. Abu, Affan, Shamsuddin, Mustaffa, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science
Online Access:http://eprints.utm.my/id/eprint/28984/
http://dx.doi.org/10.1107/S1600536810014443
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spelling my.utm.289842022-02-28T13:25:35Z http://eprints.utm.my/id/eprint/28984/ Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV) Md. Abdus, Salam Md. Abu, Affan Shamsuddin, Mustaffa Ng, Seik Weng Q Science The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. International Union of Crystallography 2010-05-01 Article PeerReviewed Md. Abdus, Salam and Md. Abu, Affan and Shamsuddin, Mustaffa and Ng, Seik Weng (2010) Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV). Acta Crystallographica Section E-Structure Reports Online, 66 (5). p. 570. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536810014443 DOI:10.1107/S1600536810014443
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic Q Science
spellingShingle Q Science
Md. Abdus, Salam
Md. Abu, Affan
Shamsuddin, Mustaffa
Ng, Seik Weng
Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)
description The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].
format Article
author Md. Abdus, Salam
Md. Abu, Affan
Shamsuddin, Mustaffa
Ng, Seik Weng
author_facet Md. Abdus, Salam
Md. Abu, Affan
Shamsuddin, Mustaffa
Ng, Seik Weng
author_sort Md. Abdus, Salam
title Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)
title_short Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)
title_full Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)
title_fullStr Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)
title_full_unstemmed Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]N)ethyl­idene]thio­semicarbazidato-[kappa]2N1,S}methyl­tin(IV)
title_sort dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-[kappa]n)ethyl­idene]thio­semicarbazidato-[kappa]2n1,s}methyl­tin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.utm.my/id/eprint/28984/
http://dx.doi.org/10.1107/S1600536810014443
_version_ 1726791440429744128

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