Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
Evidence for the synthesis of u-cyano(1,2-naphthalocyaninato)cobalt(III) (compound 3), a novel macrocyclic transition metal complex which are linked by linear bridging cyano ligands containing delocalizable pi-eletrons capable of forming polymeric stacked arrangements, via splitting off potassium cy...
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| Format: | text |
| Language: | English |
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Animo Repository
2002
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| Online Access: | https://animorepository.dlsu.edu.ph/etd_masteral/3029 |
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| Institution: | De La Salle University |
| Language: | English |
| Summary: | Evidence for the synthesis of u-cyano(1,2-naphthalocyaninato)cobalt(III) (compound 3), a novel macrocyclic transition metal complex which are linked by linear bridging cyano ligands containing delocalizable pi-eletrons capable of forming polymeric stacked arrangements, via splitting off potassium cyanide from potassium dicyano(1,2-naphthalocyaninato)cobalt(III) (compound 2), is presented. Treatment of compound 3 with pyridine leads to a monomeric complex of cobalt(III) 1,2-naphthalocyanine complex with mixed axial ligands, a novel cyano(1,2-naphthalocyaninato)cobalt(III) pyridine adduct (compound 4). Compounds are characterized by IR, UV-VIS, SEM, and mass spectroscopy. |
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