Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands

Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands

Evidence for the synthesis of u-cyano(1,2-naphthalocyaninato)cobalt(III) (compound 3), a novel macrocyclic transition metal complex which are linked by linear bridging cyano ligands containing delocalizable pi-eletrons capable of forming polymeric stacked arrangements, via splitting off potassium cy...

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Main Author: Yu, Derrick Ethelbert C.
Format: text
Language:English
Published: Animo Repository 2002
Subjects:
Cobalt compounds > Synthesis
Ligands
Phthalocyanins
Online Access:https://animorepository.dlsu.edu.ph/etd_masteral/3029
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Institution: De La Salle University
Language: English
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spelling oai:animorepository.dlsu.edu.ph:etd_masteral-98672020-12-14T10:02:25Z Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands Yu, Derrick Ethelbert C. Evidence for the synthesis of u-cyano(1,2-naphthalocyaninato)cobalt(III) (compound 3), a novel macrocyclic transition metal complex which are linked by linear bridging cyano ligands containing delocalizable pi-eletrons capable of forming polymeric stacked arrangements, via splitting off potassium cyanide from potassium dicyano(1,2-naphthalocyaninato)cobalt(III) (compound 2), is presented. Treatment of compound 3 with pyridine leads to a monomeric complex of cobalt(III) 1,2-naphthalocyanine complex with mixed axial ligands, a novel cyano(1,2-naphthalocyaninato)cobalt(III) pyridine adduct (compound 4). Compounds are characterized by IR, UV-VIS, SEM, and mass spectroscopy. 2002-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/etd_masteral/3029 Master's Theses English Animo Repository Cobalt compounds--Synthesis Ligands Phthalocyanins
institution De La Salle University
building De La Salle University Library
continent Asia
country Philippines
Philippines
content_provider De La Salle University Library
collection DLSU Institutional Repository
language English
topic Cobalt compounds--Synthesis
Ligands
Phthalocyanins
spellingShingle Cobalt compounds--Synthesis
Ligands
Phthalocyanins
Yu, Derrick Ethelbert C.
Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
description Evidence for the synthesis of u-cyano(1,2-naphthalocyaninato)cobalt(III) (compound 3), a novel macrocyclic transition metal complex which are linked by linear bridging cyano ligands containing delocalizable pi-eletrons capable of forming polymeric stacked arrangements, via splitting off potassium cyanide from potassium dicyano(1,2-naphthalocyaninato)cobalt(III) (compound 2), is presented. Treatment of compound 3 with pyridine leads to a monomeric complex of cobalt(III) 1,2-naphthalocyanine complex with mixed axial ligands, a novel cyano(1,2-naphthalocyaninato)cobalt(III) pyridine adduct (compound 4). Compounds are characterized by IR, UV-VIS, SEM, and mass spectroscopy.
format text
author Yu, Derrick Ethelbert C.
author_facet Yu, Derrick Ethelbert C.
author_sort Yu, Derrick Ethelbert C.
title Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
title_short Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
title_full Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
title_fullStr Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
title_full_unstemmed Synthesis of a novel cobalt (III) 1,2-naphthalocyanine complex with mixed axial ligands
title_sort synthesis of a novel cobalt (iii) 1,2-naphthalocyanine complex with mixed axial ligands
publisher Animo Repository
publishDate 2002
url https://animorepository.dlsu.edu.ph/etd_masteral/3029
_version_ 1712575100648161280

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