Electronic effects in oxidation reactions utilizing dinuclear copper complexes with the Bis[3-[2-hydroxybenzylldeneamino)phenyll sulfone ligand

• Main Authors: Guidoto, Armando M., Jr., Reyes, Ronald L., Kashihara, Riyo, Kurusu, Yasuhiko, Masuyama, Yoshiro
• Format: text
• Published: Animo Repository 2014
• Subjects: Complex compounds; Oxidation; Chemistry
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/8728
• Institution: De La Salle University

Copper acetate and the ligands bis[3-(3-tert-butyl-2-hydroxy-5-methoxybenzylidene-amino)phenyl] sulfone and bis[3-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)phenyl] sulfone were reacted to form the complexes with 2:1 copper:ligand ratio, Cu2[B(t-Bu) (OMe)BAPS](u-OCH3)2 (4) and with 2:2 copper:liga...