Possible Cobalt-Cobalt Bridging by a Hemiacetal in the Dinuclear Cobalt Complex Bearing the Ligand Bis(3-(2-pyridylmethyleneamino)phenyl) Sulfone

• Main Authors: Guidote, Armando M, Jr, Imajo, Tomoko, Kurusu, Yasuhiko, Masuyama, Yoshiro
• Format: text
• Published: Archīum Ateneo 2003
• Subjects: dinuclear; cobalt; complex; synthesis; Analytical Chemistry; Chemistry
• Online Access: https://archium.ateneo.edu/chemistry-faculty-pubs/49; https://archium.ateneo.edu/cgi/viewcontent.cgi?article=1048&context=chemistry-faculty-pubs
• Institution: Ateneo De Manila University

A dinuclear cobalt complex bearing the ligand bis(3-(2-pyridylmethyleneamino)phenyl) sulfone (BPMAPS) was prepared. It is proposed that the structure of this is [Coz(BPMAPS)(m-0AcMhemi-Et)]PF6 wherein the cobalt centers are bridged by two carboxylato groups in m-fashion and a hemiacetal with an etho...