Metal induced cleavage of amide bonds. Part 3, Cleavage of aromatic amides and isolation of [cis-α-Co(trien) (salicylamide)](ClO4)2 (I), Co(tren)(pyrazine-2-carboxylato)](ClO4)2·2H2O (II) and [Co(tren)(pyrazine-2,3-dicarboxylatomonoamide)](ClO4)Cl (III)

Metal induced cleavage of amide bonds. Part 3, Cleavage of aromatic amides and isolation of [cis-α-Co(trien) (salicylamide)](ClO4)2 (I), Co(tren)(pyrazine-2-carboxylato)](ClO4)2·2H2O (II) and [Co(tren)(pyrazine-2,3-dicarboxylatomonoamide)](ClO4)Cl (III)

Three aromatic amides were allowed to interact with cis-[dichloro(N4)Co]+ cations in water solutions at controlled pH ranging from 7.0 to 7.5. N4 is a linear or a branched tetra-amine, such as trien or tren (trien = 1,4,7,10-tetraazadecane; tren = tris-(2-aminoethyl)amine). In one case(II), the effe...

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Bibliographic Details
Main Authors: Mukhapadhyay, Uday, Galian, Richard Anthony F., Bernal, Ivan
Format: text
Published: Animo Repository 2009
Subjects:
Scission (Chemistry)
Amides
Diamonds
Nuclear magnetic resonance spectroscopy
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/11318
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Institution: De La Salle University

Internet

https://animorepository.dlsu.edu.ph/faculty_research/11318

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