Metal induced cleavage of amide bonds. Part 3, Cleavage of aromatic amides and isolation of [cis-α-Co(trien) (salicylamide)](ClO4)2 (I), Co(tren)(pyrazine-2-carboxylato)](ClO4)2·2H2O (II) and [Co(tren)(pyrazine-2,3-dicarboxylatomonoamide)](ClO4)Cl (III)
Three aromatic amides were allowed to interact with cis-[dichloro(N4)Co]+ cations in water solutions at controlled pH ranging from 7.0 to 7.5. N4 is a linear or a branched tetra-amine, such as trien or tren (trien = 1,4,7,10-tetraazadecane; tren = tris-(2-aminoethyl)amine). In one case(II), the effe...
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| Main Authors: | , , |
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| Format: | text |
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Animo Repository
2009
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| Online Access: | https://animorepository.dlsu.edu.ph/faculty_research/11318 |
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| Institution: | De La Salle University |