Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives

Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives

The p-acetoxybenzylsulfanyl protecting group is compatible with the triethylphosphite mediated cross-coupling of 4,5-bis(alkylsulfanyl)-1,3-dithiol-2-ones, providing access to bis(protected)tetrathiafulvalenes, and thus to tetrathiafulvalenedithiolate dianion 10, which can be alkylated to give unsym...

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Main Authors: Gemmell, Colin, Janairo, Gerardo C., Kilburn, Jeremy D., Ueck, Henning, Underhill, Allan E.
Format: text
Published: Animo Repository 1994
Subjects:
Tetrathiafulvalene
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/6734
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Institution: De La Salle University
id oai:animorepository.dlsu.edu.ph:faculty_research-7348
record_format eprints
spelling oai:animorepository.dlsu.edu.ph:faculty_research-73482022-08-31T02:19:54Z Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives Gemmell, Colin Janairo, Gerardo C. Kilburn, Jeremy D. Ueck, Henning Underhill, Allan E. The p-acetoxybenzylsulfanyl protecting group is compatible with the triethylphosphite mediated cross-coupling of 4,5-bis(alkylsulfanyl)-1,3-dithiol-2-ones, providing access to bis(protected)tetrathiafulvalenes, and thus to tetrathiafulvalenedithiolate dianion 10, which can be alkylated to give unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives. 1994-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/6734 Faculty Research Work Animo Repository Tetrathiafulvalene Chemistry
institution De La Salle University
building De La Salle University Library
continent Asia
country Philippines
Philippines
content_provider De La Salle University Library
collection DLSU Institutional Repository
topic Tetrathiafulvalene
Chemistry
spellingShingle Tetrathiafulvalene
Chemistry
Gemmell, Colin
Janairo, Gerardo C.
Kilburn, Jeremy D.
Ueck, Henning
Underhill, Allan E.
Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
description The p-acetoxybenzylsulfanyl protecting group is compatible with the triethylphosphite mediated cross-coupling of 4,5-bis(alkylsulfanyl)-1,3-dithiol-2-ones, providing access to bis(protected)tetrathiafulvalenes, and thus to tetrathiafulvalenedithiolate dianion 10, which can be alkylated to give unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives.
format text
author Gemmell, Colin
Janairo, Gerardo C.
Kilburn, Jeremy D.
Ueck, Henning
Underhill, Allan E.
author_facet Gemmell, Colin
Janairo, Gerardo C.
Kilburn, Jeremy D.
Ueck, Henning
Underhill, Allan E.
author_sort Gemmell, Colin
title Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
title_short Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
title_full Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
title_fullStr Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
title_full_unstemmed Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
title_sort synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
publisher Animo Repository
publishDate 1994
url https://animorepository.dlsu.edu.ph/faculty_research/6734
_version_ 1767196552637448192

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