Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
The p-acetoxybenzylsulfanyl protecting group is compatible with the triethylphosphite mediated cross-coupling of 4,5-bis(alkylsulfanyl)-1,3-dithiol-2-ones, providing access to bis(protected)tetrathiafulvalenes, and thus to tetrathiafulvalenedithiolate dianion 10, which can be alkylated to give unsym...
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Main Authors: | Gemmell, Colin, Janairo, Gerardo C., Kilburn, Jeremy D., Ueck, Henning, Underhill, Allan E. |
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Format: | text |
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Animo Repository
1994
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Online Access: | https://animorepository.dlsu.edu.ph/faculty_research/6734 |
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Institution: | De La Salle University |
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