Ferrocene-containing [1]-, [2]-, [3]- and [4]rotaxanes synthesized from a common precursor
The Cu-catalyzed reaction of a dialkylammonium, having ferrocenyl and hexynyl end groups, FcCH2NH2CH2C6H4–4-O(CH2)4CCH]PF6 (Fc = Fe(C5H4)(C5H5)), with a crown ether having an azidemethyl side-arm yields a [1]rotaxane composed of a single molecule. The crystal structure of the [1]rotaxane suggests an...
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| Main Authors: | , , |
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| Format: | text |
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Archīum Ateneo
2016
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| Online Access: | https://archium.ateneo.edu/chemistry-faculty-pubs/11 https://pubs.rsc.org/ko/content/articlelanding/2016/ra/c6ra05688a/unauth#!divAbstract |
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| Institution: | Ateneo De Manila University |