Behavior of rigid macromolecules in self‐assembly at an interface

• Main Authors: Enriquez, Erwin, Gray, Kimberley H, Guarisco, Victoria F, Linton, Richard W, Mar, Kevin D, Samulski, Edward T
• Format: text
• Published: Archīum Ateneo 1992
• Subjects: Chemistry; Polymer Chemistry; Radiochemistry
• Online Access: https://archium.ateneo.edu/chemistry-faculty-pubs/54; https://avs.scitation.org/doi/10.1116/1.577909
• Institution: Ateneo De Manila University

Self‐assembly (SA) on gold substrates of α‐helical poly(γ‐benzyl‐L‐glutamate) [(PBLG); molecular weight ∼20 000 kd] with a disulfide moiety attached at its N‐terminus (PBLGSS) was investigated. The SA films were compared with control experiments using unlabeled physisorbed (PS) PBLG and Langmuir–Blo...