Mechanistic aspects of the nickel‐catalyzed addition reaction of alkenyl‐zirconium reagents to cyclopropyl ketones
Nickel‐catalyzed addition of alkenylzirconium species to cyclopropyl ketones proceeds by an electron transfer mechanism. One‐electron reduction of the substrate leads to a ketyl which may either couple to give the 1, 2‐addition product or undergo a second one‐electron reduction, followed by rearrang...
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| Main Authors: | , , |
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| Format: | text |
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Archīum Ateneo
1980
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| Online Access: | https://archium.ateneo.edu/chemistry-faculty-pubs/118 https://onlinelibrary.wiley.com/doi/abs/10.1002/bscb.19800891015 |
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| Institution: | Ateneo De Manila University |