Gold-catalyzed cycloisomerization of 1,6,8-dienyne carbonates and esters to cis-cyclohepta-4,8-diene-fused pyrrolidines

• المؤلفون الرئيسيون: Sally, Berry, Stuart Neil, Chan, Philip Wai Hong, Rao, Weidong
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Physics::Atomic physics::Solid state physics
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/100556; http://hdl.handle.net/10220/24142

A synthetic approach that provides access to cis-cyclohepta-4,8-diene-fused pyrrolidines efficiently through AuI-catalyzed cycloisomerization of 1,6,8-dienyne carbonates and esters at a low catalyst loading of 2 mol % is reported. Starting carbonates and esters with a pendant alkyl group on the term...