Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides
Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route for the synthesis of (Z,E)-dienamides in excellent yields with good stereoselectivity. The catalytic systems allowed oxidative olefination o...
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sg-ntu-dr.10356-1008202020-03-07T12:34:49Z Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides Zhang, Jian. Loh, Teck-Peng. School of Physical and Mathematical Sciences Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route for the synthesis of (Z,E)-dienamides in excellent yields with good stereoselectivity. The catalytic systems allowed oxidative olefination of a wide range of alkenes bearing different functional groups, such as CO2R, COMe, SO2Ph, aryl, CONHBn, CN, PO(OEt)2, as well as Weinreb amide. 2013-07-10T02:14:17Z 2019-12-06T20:28:54Z 2013-07-10T02:14:17Z 2019-12-06T20:28:54Z 2012 2012 Journal Article Zhang, J., Loh, T.-P. (2012). Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z,E)-dienamides. Chemical Communications, 48(91), 11232-11234. https://hdl.handle.net/10356/100820 http://hdl.handle.net/10220/11079 10.1039/c2cc36137j en Chemical communications © 2012 The Royal Society of Chemistry. |
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Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route for the synthesis of (Z,E)-dienamides in excellent yields with good stereoselectivity. The catalytic systems allowed oxidative olefination of a wide range of alkenes bearing different functional groups, such as CO2R, COMe, SO2Ph, aryl, CONHBn, CN, PO(OEt)2, as well as Weinreb amide. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Zhang, Jian. Loh, Teck-Peng. |
| format |
Article |
| author |
Zhang, Jian. Loh, Teck-Peng. |
| spellingShingle |
Zhang, Jian. Loh, Teck-Peng. Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides |
| author_sort |
Zhang, Jian. |
| title |
Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides |
| title_short |
Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides |
| title_full |
Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides |
| title_fullStr |
Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides |
| title_full_unstemmed |
Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (Z,E)-dienamides |
| title_sort |
ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes : efficient access to (z,e)-dienamides |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/100820 http://hdl.handle.net/10220/11079 |
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1681034038616260608 |