Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N–O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.
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| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/100956 http://hdl.handle.net/10220/11055 |
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| Institution: | Nanyang Technological University |
| Language: | English |