Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles

Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N–O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.

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Main Authors:	Qi, Xinxin, Xu, Xianxiu, Park, Cheol-Min
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2013
Online Access:	https://hdl.handle.net/10356/100956 http://hdl.handle.net/10220/11055
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-1009562020-03-07T12:34:50Z Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles Qi, Xinxin Xu, Xianxiu Park, Cheol-Min School of Physical and Mathematical Sciences Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N–O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition. 2013-07-09T04:15:55Z 2019-12-06T20:31:25Z 2013-07-09T04:15:55Z 2019-12-06T20:31:25Z 2012 2012 Journal Article Qi, X., Xu, X., Park, C.-M. (2012). Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles. Chemical Communications, 48, 3996-3998. https://hdl.handle.net/10356/100956 http://hdl.handle.net/10220/11055 10.1039/c2cc30490b en Chemical communications © 2012 The Royal Society of Chemistry.
institution	Nanyang Technological University
building	NTU Library
country	Singapore
collection	DR-NTU
language	English
description	Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N–O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Qi, Xinxin Xu, Xianxiu Park, Cheol-Min
format	Article
author	Qi, Xinxin Xu, Xianxiu Park, Cheol-Min
spellingShingle	Qi, Xinxin Xu, Xianxiu Park, Cheol-Min Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
author_sort	Qi, Xinxin
title	Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
title_short	Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
title_full	Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
title_fullStr	Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
title_full_unstemmed	Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
title_sort	facile synthesis of 2-alkyl/aryloxy-2h-azirines and their application in the synthesis of pyrroles
publishDate	2013
url	https://hdl.handle.net/10356/100956 http://hdl.handle.net/10220/11055
_version_	1681049798914867200

Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles

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